Compound Identification
SMILES
CC(C)\C=C(/C)[C@H]1O[C@@]2(C[C@@H]3C[C@@H](C\C=C(C)\C[C@@H](C)\C=C\C=C4/CO[C@@H]5[C@H](OC(=O)C6=CC=C(C=C6)[Si](C)(C6=CC=CC=C6)C6=CC=CC=C6)C(C)=C[C@@H](C(=O)O3)[C@]45O)O2)CC(=O)[C@@H]1C
InChIKey
InChIKey=SSYOFETVEPLBCS-VZZMACMDSA-N
Formula
C56H66O9Si
Mass
911.22
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
-
Superclass
Phenylpropanoids and polyketides
-
Class
Macrolides and analogues
- Subclass Milbemycins
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Class
Macrolides and analogues
-
Superclass
Phenylpropanoids and polyketides
Kingdom
Organic compounds
Superclass
Phenylpropanoids and polyketides
Class
Macrolides and analogues
Subclass
Milbemycins
Intermediate Tree Nodes
Not available
Direct Parent
Milbemycins
Alternative Parents
Benzoic acid esters Benzoyl derivatives Alkylarylsilanes Ketals Oxanes Dicarboxylic acids and derivatives Tertiary alcohols Oxolanes Lactones Cyclic ketones Carboxylic acid esters Oxacyclic compounds Organic metalloid salts Dialkyl ethers Hydrocarbon derivatives Alkylsilanes Organic oxides Aldehydes
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Milbemycin - Benzoate ester - Benzoic acid or derivatives - Benzoyl - Alkylarylsilane - Ketal - Monocyclic benzene moiety - Dicarboxylic acid or derivatives - Oxane - Benzenoid - Oxolane - Tertiary alcohol - Carboxylic acid ester - Lactone - Ketone - Cyclic ketone - Organic metalloid salt - Oxacycle - Organoheterocyclic compound - Carboxylic acid derivative - Acetal - Ether - Dialkyl ether - Organic oxygen compound - Organic metalloid moeity - Organooxygen compound - Carbonyl group - Alkylsilane - Organosilicon compound - Hydrocarbon derivative - Organic oxide - Aldehyde - Alcohol - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as milbemycins. These are a group of macrolides with a structure containing a 16-membered lactone ring fused to a 1,7-dioxaspiroundecane ring system and to either a benzofuran (or hydrogenated derivative thereof). In some cases (e.g. Milbemycin E), the tetrahydrofuranyl ring is missing. Milbemycins can be o-glycosylated at C13 to form Avermectins. Milbemycins are produced by Streptomyces species.
External Descriptors
Not available