Compound Identification
SMILES
CCC1=C[N+]([C@H]2C[C@]3([C@H]4C[C@@H]1[C@@H]2CO4)C(=O)NC1=C3C=CC(OC)=C1)=C(OCC(Cl)(Cl)Cl)O[Si](C)(C)C
InChIKey
InChIKey=REDULKRGAARDDI-YNBIHDICSA-O
Formula
C26H34Cl3N2O5Si
Mass
589.0
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
-
Superclass
Alkaloids and derivatives
- Class Gelsemium alkaloids
-
Superclass
Alkaloids and derivatives
Kingdom
Organic compounds
Superclass
Alkaloids and derivatives
Class
Gelsemium alkaloids
Subclass
Not available
Intermediate Tree Nodes
Not available
Direct Parent
Gelsemium alkaloids
Alternative Parents
Indolines Anisoles Tetrahydropyridines Oxepanes Alkyl aryl ethers Oxanes Trialkylheterosilanes Secondary carboxylic acid amides Lactams Oxacyclic compounds Azacyclic compounds Carboximidic acids and derivatives Dialkyl ethers Organic metalloid salts Alkyl chlorides Organonitrogen compounds Hydrocarbon derivatives Organochlorides Organic oxides Carbonyl compounds Organic cations
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Gelsemium skeleton - Indole or derivatives - Dihydroindole - Anisole - Phenol ether - Alkyl aryl ether - Oxepane - Tetrahydropyridine - Oxane - Benzenoid - Trialkylheterosilane - Carboxamide group - Lactam - Secondary carboxylic acid amide - Carboximidic acid derivative - Organoheterosilane - Carboxylic acid derivative - Dialkyl ether - Ether - Oxacycle - Azacycle - Organic metalloid salt - Organoheterocyclic compound - Organohalogen compound - Carbonyl group - Hydrocarbon derivative - Organic oxide - Organic oxygen compound - Organic metalloid moeity - Organochloride - Organonitrogen compound - Organooxygen compound - Organic nitrogen compound - Alkyl chloride - Alkyl halide - Organosilicon compound - Organic cation - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as gelsemium alkaloids. These are alkaloids with a structure that is based on the tetracyclic gelsemium skeleton. These alkaloids contain an oxindole function and a cage-like, hydroaromatic residue which is believed to arise from an intermediate related to anhydrovobasinediol by formation of a 6,20 bond and rearrangement to an oxindole. The major alkaloids in this group are related to Gelsemine; however, a smaller group, characterized by Gelsedine, lack the 6,20 bond, and have also lost C-21.
External Descriptors
Not available