Compound Identification
SMILES
CO[C@H]1C[C@@H]2N3C[C@@H](O)[C@@]2(C=C1)c1cc2OCOc2c(OC)c1C3
InChIKey
InChIKey=QAHZAHIPKNLGAS-RIOHULGPSA-N
Formula
C18H21NO5
Mass
331.368
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
- Superclass Alkaloids and derivatives
Kingdom
Organic compounds
Superclass
Alkaloids and derivatives
Class
Amaryllidaceae alkaloids
Subclass
Crinine- and Haemanthamine-type amaryllidaceae alkaloids
Intermediate Tree Nodes
Not available
Direct Parent
Crinine- and Haemanthamine-type amaryllidaceae alkaloids
Alternative Parents
Phenanthridines and derivatives Benzazepines Tetrahydroisoquinolines Indoles and derivatives Benzodioxoles Anisoles Alkyl aryl ethers Aralkylamines Azepines N-alkylpyrrolidines Trialkylamines Secondary alcohols 1,2-aminoalcohols Oxacyclic compounds Acetals Azacyclic compounds Dialkyl ethers Organopnictogen compounds Hydrocarbon derivatives
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Hemanthamine/crinine alkaloid skeleton - Benzoquinoline - Phenanthridine - Benzazepine - Tetrahydroisoquinoline - Quinoline - Benzodioxole - Indole or derivatives - Anisole - Alkyl aryl ether - Azepine - Aralkylamine - Benzenoid - N-alkylpyrrolidine - Pyrrolidine - Tertiary amine - 1,2-aminoalcohol - Tertiary aliphatic amine - Secondary alcohol - Acetal - Oxacycle - Azacycle - Dialkyl ether - Ether - Organoheterocyclic compound - Hydrocarbon derivative - Organopnictogen compound - Organooxygen compound - Alcohol - Organic nitrogen compound - Amine - Organic oxygen compound - Organonitrogen compound - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as crinine- and haemanthamine-type amaryllidaceae alkaloids. These are amaryllidaceae alkaloids compounds with a structure based on the crinine or haemanthamine backbone. Both backbones have a common 5,10b-ethano bridge moiety in their frameworks, which is a very significant taxonomic feature, and the configurations of the 5,10b-ethano bridge are opposite to each other.
External Descriptors
Not available