Compound Identification
SMILES
C\C=C1/C[N@@+]2([O-])[C@H]3C[C@@]45C[C@H]3[C@H]1C[C@H]2[C@@H]4N(C[NH2+][O-])C1=CC=CC=C51
InChIKey
InChIKey=OTTGRXWSDFIXQP-WGCUJWMGSA-N
Formula
C20H25N3O2
Mass
339.439
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
- Superclass Alkaloids and derivatives
Kingdom
Organic compounds
Superclass
Alkaloids and derivatives
Class
Ajmaline-sarpagine alkaloids
Subclass
Not available
Intermediate Tree Nodes
Not available
Direct Parent
Ajmaline-sarpagine alkaloids
Alternative Parents
Beta carbolines Quinolizidines Quinuclidines Dialkylarylamines Azepanes Piperidines Benzenoids Trialkyl amine oxides Trisubstituted amine oxides and derivatives C-nitroso compounds Azacyclic compounds Organic salts Organic oxides Hydrocarbon derivatives Organic cations
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Sarpagine-skeleton - Ajmaline-skeleton - Beta-carboline - Pyridoindole - Quinolizidine - Indole or derivatives - Dialkylarylamine - Quinuclidine - Azepane - Piperidine - Benzenoid - Trialkyl amine oxide - Organic nitroso compound - N-oxide - C-nitroso compound - Azacycle - Organoheterocyclic compound - Trisubstituted n-oxide - Hydrocarbon derivative - Organic nitrogen compound - Organonitrogen compound - Organic oxygen compound - Organic salt - Organic oxide - Organic cation - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as ajmaline-sarpagine alkaloids. These are organic compounds containing either of the ajmalan, sarpagan skeleton, or derivative thereof. The Sarpagine (Akuammidine) group, based on the sarpagan nucleus, arises from bond formation between C-16 and C-5 of the corynantheine precursor. Ajmaline alkaloids are based on a 17,19-secoyohimban skeleton (oxayohimban) which is invariably present as an ether.
External Descriptors
Not available