Structure Information
Structure

Compound Identification

SMILES

C\C=C1/[C@@H]2C[C@@H]3N([C@H]4C[C@]5([C@H](OC(C)=O)C24)C3=NC2=CC=CC=C52)[C@@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O

InChIKey

InChIKey=OSJPGOJPRNTSHP-ICYIRATMSA-N

Formula

C27H32N2O8

Mass

512.559

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Taxonomic Classification

Taxonomy Tree

Kingdom

Organic compounds

Superclass

Alkaloids and derivatives

Class

Ajmaline-sarpagine alkaloids

Subclass

Not available

Intermediate Tree Nodes

Not available

Direct Parent

Ajmaline-sarpagine alkaloids

Alternative Parents

Molecular Framework

Aromatic heteropolycyclic compounds

Substituents

Sarpagine-skeleton - Hexose monosaccharide - Glycosyl compound - O-glycosyl compound - Quinolizidine - 3-alkylindole - Indole or derivatives - Quinuclidine - Azepane - Monosaccharide - Oxane - Piperidine - Benzenoid - Secondary alcohol - Carboxylic acid ester - Ketimine - Propargyl-type 1,3-dipolar organic compound - Organic 1,3-dipolar compound - Organoheterocyclic compound - Carboxylic acid derivative - Azacycle - Monocarboxylic acid or derivatives - Acetal - Oxacycle - Polyol - Hydrocarbon derivative - Imine - Organic oxide - Primary alcohol - Carbonyl group - Organic oxygen compound - Organonitrogen compound - Organooxygen compound - Organic nitrogen compound - Alcohol - Organopnictogen compound - Aromatic heteropolycyclic compound

Description

This compound belongs to the class of organic compounds known as ajmaline-sarpagine alkaloids. These are organic compounds containing either of the ajmalan, sarpagan skeleton, or derivative thereof. The Sarpagine (Akuammidine) group, based on the sarpagan nucleus, arises from bond formation between C-16 and C-5 of the corynantheine precursor. Ajmaline alkaloids are based on a 17,19-secoyohimban skeleton (oxayohimban) which is invariably present as an ether.

External Descriptors

CHEBI:17400 : beta-D-glucoside
KEGG (C02074) : Indole alkaloids

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