Compound Identification
SMILES
C\C=C1/[C@@H]2C[C@@H]3N([C@H]4C[C@]5([C@H](OC(C)=O)C24)C3=NC2=CC=CC=C52)[C@@H]1O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O
InChIKey
InChIKey=OSJPGOJPRNTSHP-ICYIRATMSA-N
Formula
C27H32N2O8
Mass
512.559
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
- Superclass Alkaloids and derivatives
Kingdom
Organic compounds
Superclass
Alkaloids and derivatives
Class
Ajmaline-sarpagine alkaloids
Subclass
Not available
Intermediate Tree Nodes
Not available
Direct Parent
Ajmaline-sarpagine alkaloids
Alternative Parents
Hexoses O-glycosyl compounds 3-alkylindoles Quinolizidines Quinuclidines Azepanes Benzenoids Oxanes Piperidines Ketimines Carboxylic acid esters Secondary alcohols Polyols Monocarboxylic acids and derivatives Propargyl-type 1,3-dipolar organic compounds Oxacyclic compounds Acetals Azacyclic compounds Organopnictogen compounds Organic oxides Hydrocarbon derivatives Primary alcohols Carbonyl compounds
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Sarpagine-skeleton - Hexose monosaccharide - Glycosyl compound - O-glycosyl compound - Quinolizidine - 3-alkylindole - Indole or derivatives - Quinuclidine - Azepane - Monosaccharide - Oxane - Piperidine - Benzenoid - Secondary alcohol - Carboxylic acid ester - Ketimine - Propargyl-type 1,3-dipolar organic compound - Organic 1,3-dipolar compound - Organoheterocyclic compound - Carboxylic acid derivative - Azacycle - Monocarboxylic acid or derivatives - Acetal - Oxacycle - Polyol - Hydrocarbon derivative - Imine - Organic oxide - Primary alcohol - Carbonyl group - Organic oxygen compound - Organonitrogen compound - Organooxygen compound - Organic nitrogen compound - Alcohol - Organopnictogen compound - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as ajmaline-sarpagine alkaloids. These are organic compounds containing either of the ajmalan, sarpagan skeleton, or derivative thereof. The Sarpagine (Akuammidine) group, based on the sarpagan nucleus, arises from bond formation between C-16 and C-5 of the corynantheine precursor. Ajmaline alkaloids are based on a 17,19-secoyohimban skeleton (oxayohimban) which is invariably present as an ether.
External Descriptors
CHEBI:17400 :
beta-D-glucoside
KEGG (C02074) :
Indole alkaloids