Compound Identification
SMILES
C\C=C1/C[N@@+]2([O-])[C@H]3C[C@@]45C[C@H]3[C@H]1C[C@H]2[C@@H]4N(CN[O-])C1=CC=CC=C51
InChIKey
InChIKey=LTWOKQKZIJWHDQ-WGCUJWMGSA-N
Formula
C20H24N3O2
Mass
338.432
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
- Superclass Alkaloids and derivatives
Kingdom
Organic compounds
Superclass
Alkaloids and derivatives
Class
Ajmaline-sarpagine alkaloids
Subclass
Not available
Intermediate Tree Nodes
Not available
Direct Parent
Ajmaline-sarpagine alkaloids
Alternative Parents
Beta carbolines Quinolizidines Quinuclidines Dialkylarylamines Azepanes Piperidines Benzenoids Trialkyl amine oxides Trisubstituted amine oxides and derivatives Azacyclic compounds Organic salts Organic oxides Hydrocarbon derivatives Organic cations
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Sarpagine-skeleton - Ajmaline-skeleton - Beta-carboline - Pyridoindole - Quinolizidine - Indole or derivatives - Dialkylarylamine - Quinuclidine - Azepane - Piperidine - Benzenoid - Trialkyl amine oxide - N-oxide - Azacycle - Organoheterocyclic compound - Trisubstituted n-oxide - Organonitrogen compound - Organic oxygen compound - Hydrocarbon derivative - Organic oxide - Organic nitrogen compound - Organic salt - Organic cation - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as ajmaline-sarpagine alkaloids. These are organic compounds containing either of the ajmalan, sarpagan skeleton, or derivative thereof. The Sarpagine (Akuammidine) group, based on the sarpagan nucleus, arises from bond formation between C-16 and C-5 of the corynantheine precursor. Ajmaline alkaloids are based on a 17,19-secoyohimban skeleton (oxayohimban) which is invariably present as an ether.
External Descriptors
Not available