Structure Information
Structure

Compound Identification

SMILES

COC1=CC2=C(C=C1)[C@]13C[C@H]4C([C@H]5C[C@@H]([C@@H]1N2C)N4C\C5=C\C)C3=O

InChIKey

InChIKey=LEHVAVBEMNLCAM-JHRDMWOESA-N

Formula

C21H24N2O2

Mass

336.435

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Taxonomic Classification

Taxonomy Tree

Kingdom

Organic compounds

Superclass

Alkaloids and derivatives

Class

Ajmaline-sarpagine alkaloids

Subclass

Not available

Intermediate Tree Nodes

Not available

Direct Parent

Ajmaline-sarpagine alkaloids

Alternative Parents

Molecular Framework

Aromatic heteropolycyclic compounds

Substituents

Sarpagine-skeleton - Pyridoindole - Beta-carboline - Quinolizidine - Indole or derivatives - Anisole - Dialkylarylamine - Tertiary aliphatic/aromatic amine - Quinuclidine - Phenol ether - Aralkylamine - Alkyl aryl ether - Azepane - Benzenoid - Piperidine - Tertiary aliphatic amine - Tertiary amine - Ketone - Azacycle - Ether - Organoheterocyclic compound - Organic oxygen compound - Carbonyl group - Organic nitrogen compound - Hydrocarbon derivative - Organic oxide - Amine - Organooxygen compound - Organonitrogen compound - Aromatic heteropolycyclic compound

Description

This compound belongs to the class of organic compounds known as ajmaline-sarpagine alkaloids. These are organic compounds containing either of the ajmalan, sarpagan skeleton, or derivative thereof. The Sarpagine (Akuammidine) group, based on the sarpagan nucleus, arises from bond formation between C-16 and C-5 of the corynantheine precursor. Ajmaline alkaloids are based on a 17,19-secoyohimban skeleton (oxayohimban) which is invariably present as an ether.

External Descriptors

Not available

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