Compound Identification
SMILES
COC1=CC=CC2=C1N[C@H]1[C@@H]3C[C@@H]4[C@H]5[C@H](C[C@]21[C@@H]5O)N3C\C4=C\C
InChIKey
InChIKey=HTETYMBEAKZXSG-JVCOJETQSA-N
Formula
C20H24N2O2
Mass
324.424
Taxonomic Classification
Taxonomy Tree
-
Kingdom
Organic compounds
- Superclass Alkaloids and derivatives
Kingdom
Organic compounds
Superclass
Alkaloids and derivatives
Class
Ajmaline-sarpagine alkaloids
Subclass
Not available
Intermediate Tree Nodes
Not available
Direct Parent
Ajmaline-sarpagine alkaloids
Alternative Parents
Beta carbolines Quinolizidines Indolines Quinuclidines Anisoles Secondary alkylarylamines Azepanes Aralkylamines Alkyl aryl ethers Piperidines Trialkylamines Secondary alcohols Cyclic alcohols and derivatives Azacyclic compounds Organopnictogen compounds Hydrocarbon derivatives
Molecular Framework
Aromatic heteropolycyclic compounds
Substituents
Sarpagine-skeleton - Pyridoindole - Beta-carboline - Quinolizidine - Dihydroindole - Indole or derivatives - Quinuclidine - Anisole - Aralkylamine - Secondary aliphatic/aromatic amine - Azepane - Alkyl aryl ether - Benzenoid - Piperidine - Cyclic alcohol - Tertiary aliphatic amine - Tertiary amine - Secondary alcohol - Azacycle - Organoheterocyclic compound - Secondary amine - Ether - Organic nitrogen compound - Organic oxygen compound - Organopnictogen compound - Hydrocarbon derivative - Organooxygen compound - Organonitrogen compound - Amine - Alcohol - Aromatic heteropolycyclic compound
Description
This compound belongs to the class of organic compounds known as ajmaline-sarpagine alkaloids. These are organic compounds containing either of the ajmalan, sarpagan skeleton, or derivative thereof. The Sarpagine (Akuammidine) group, based on the sarpagan nucleus, arises from bond formation between C-16 and C-5 of the corynantheine precursor. Ajmaline alkaloids are based on a 17,19-secoyohimban skeleton (oxayohimban) which is invariably present as an ether.
External Descriptors
Not available