Structure Information
Structure

Compound Identification

SMILES

COC1=CC2=C(C=C1)[C@]1(CC3[C@H]4CO[C@H]1C[C@H]4[C@@]1(CN31)[C@@H](C)O)C(=O)N2

InChIKey

InChIKey=BINNTLDJZAZYMH-ULQBSYSVSA-N

Formula

C20H24N2O4

Mass

356.422

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Taxonomic Classification

Taxonomy Tree

Kingdom

Organic compounds

Superclass

Alkaloids and derivatives

Class

Gelsemium alkaloids

Subclass

Not available

Intermediate Tree Nodes

Not available

Direct Parent

Gelsemium alkaloids

Alternative Parents

Molecular Framework

Aromatic heteropolycyclic compounds

Substituents

Gelsemium skeleton - C21-norgelsemium skeleton - Indole or derivatives - Dihydroindole - Anisole - Phenol ether - Alkyl aryl ether - Oxepane - Aralkylamine - Oxane - Benzenoid - N-alkylpyrrolidine - Piperidine - 1,3-aminoalcohol - Pyrrolidine - Carboxamide group - Amino acid or derivatives - Lactam - 1,2-aminoalcohol - Tertiary aliphatic amine - Tertiary amine - Secondary carboxylic acid amide - Secondary alcohol - Azacycle - Oxacycle - Aziridine - Organoheterocyclic compound - Carboxylic acid derivative - Dialkyl ether - Ether - Alcohol - Carbonyl group - Organic oxygen compound - Organic nitrogen compound - Organic oxide - Amine - Organonitrogen compound - Organooxygen compound - Hydrocarbon derivative - Aromatic heteropolycyclic compound

Description

This compound belongs to the class of organic compounds known as gelsemium alkaloids. These are alkaloids with a structure that is based on the tetracyclic gelsemium skeleton. These alkaloids contain an oxindole function and a cage-like, hydroaromatic residue which is believed to arise from an intermediate related to anhydrovobasinediol by formation of a 6,20 bond and rearrangement to an oxindole. The major alkaloids in this group are related to Gelsemine; however, a smaller group, characterized by Gelsedine, lack the 6,20 bond, and have also lost C-21.

External Descriptors

Not available

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